Serial3 Not Working

Open a new commandline (Windows + R → cmd.exe). Then change-directory (cd) into your PlatformIO’s openocd installation

cd .platformio\packages\tool-openocd

Then just execute the OpenOCD command that PlatformIO would to connect to the chip

bin\openocd -s scripts -f interface/stlink.cfg  -c "set CHIPNAME at91sam3X8E; set CPUTAPID 0x2ba01477" -f target/at91sam3ax_8x.cfg

What does just that output?