ESP32 timeout error: pin in use by WiFi, but it's not in the program

The first version of this program had analog inputs at GPIO 2 and GPIO 4.

I get this error
[E][esp32-hal-adc.c:135] __analogRead(): GPIO2: ESP_ERR_TIMEOUT: ADC2 is in use by Wi-Fi.
[E][esp32-hal-adc.c:135] __analogRead(): GPIO4: ESP_ERR_TIMEOUT: ADC2 is in use by Wi-Fi.

I moved them down. IO2 and IO4 are not in this program.
What the heck??

Using WeMos D1R32.
Code:

#include <Arduino.h>
/*
  Rui Santos
  Complete project details at https://RandomNerdTutorials.com/esp32-esp-now-wi-fi-web-server/
  
  Permission is hereby granted, free of charge, to any person obtaining a copy
  of this software and associated documentation files.
  
  The above copyright notice and this permission notice shall be included in all
  copies or substantial portions of the Software.
*/

#include <esp_now.h>
#include <esp_wifi.h>
#include <WiFi.h>
#include <Adafruit_Sensor.h>
#include "Adafruit_BME680.h"
#include "Adafruit_SGP30.h"

#define SEALEVELPRESSURE_HPA (1013.25)

Adafruit_SGP30 sgp;

Adafruit_BME680 bme; // I2C

// Set your Board ID (ESP32 Sender #1 = BOARD_ID 1, ESP32 Sender #2 = BOARD_ID 2, etc)
#define BOARD_ID 2

//MAC Address of the receiver
uint8_t broadcastAddress[] = {0xFC, 0xF5, 0xC4, 0x2F, 0xA1, 0x04};

//Structure example to send data
//Must match the receiver structure
typedef struct struct_message
{
  int id;
  float completed;
  float temperature;
  float humidity;
  float pressure;
  float altitude;
  float LPG;
  float CO;
  float CO2;
  float NH3;
  float NO2;
  float VOC;
  float TVOC;
  float H2;
  float EtOH;
  int readingId;
} struct_message;

//Create a struct_message called myData
struct_message myData;

unsigned long previousMillis = 0; // Stores last time temperature was published
const long interval = 10000;      // Interval at which to publish sensor readings

unsigned int readingId = 0;

// Insert your SSID
constexpr char WIFI_SSID[] = "Fishing24";

int32_t getWiFiChannel(const char *ssid)
{
  if (int32_t n = WiFi.scanNetworks())
  {
    for (uint8_t i = 0; i < n; i++)
    {
      if (!strcmp(ssid, WiFi.SSID(i).c_str()))
      {
        return WiFi.channel(i);
      }
    }
  }
  return 0;
}

// callback when data is sent
void OnDataSent(const uint8_t *mac_addr, esp_now_send_status_t status)
{
  Serial.print("\r\nLast Packet Send Status:\t");
  Serial.println(status == ESP_NOW_SEND_SUCCESS ? "Delivery Success" : "Delivery Fail");
}

void setup()
{
  Serial.begin(9600);
  //Init Serial Monitor
  while (!Serial)
    ;
  Serial.println(F("BME680 test"));

  if (!bme.begin())
  {
    Serial.println(F("BME680 not found"));
    while (1)
      ;
  }

  Serial.println("SGP30 test");

  if (!sgp.begin())
  {
    Serial.println("SGP30 not found :(");
    while (1)
      ;
  }

  pinMode(35, INPUT);
  pinMode(34, INPUT);
  pinMode(36, INPUT);
  pinMode(39, INPUT);

  // Set device as a Wi-Fi Station and set channel
  WiFi.mode(WIFI_STA);

  int32_t channel = getWiFiChannel(WIFI_SSID);

  WiFi.printDiag(Serial); // Uncomment to verify channel number before
  esp_wifi_set_promiscuous(true);
  esp_wifi_set_channel(channel, WIFI_SECOND_CHAN_NONE);
  esp_wifi_set_promiscuous(false);
  WiFi.printDiag(Serial); // Uncomment to verify channel change after

  //Init ESP-NOW
  if (esp_now_init() != ESP_OK)
  {
    Serial.println("Error initializing ESP-NOW");
    return;
  }

  // Once ESPNow is successfully Init, we will register for Send CB to
  // get the status of Trasnmitted packet
  esp_now_register_send_cb(OnDataSent);

  //Register peer
  esp_now_peer_info_t peerInfo;
  memcpy(peerInfo.peer_addr, broadcastAddress, 6);
  peerInfo.encrypt = false;

  //Add peer
  if (esp_now_add_peer(&peerInfo) != ESP_OK)
  {
    Serial.println("Failed to add peer");
    return;
  }
  // Set up oversampling and filter initialization
  bme.setTemperatureOversampling(BME680_OS_8X);
  bme.setHumidityOversampling(BME680_OS_2X);
  bme.setPressureOversampling(BME680_OS_4X);
  bme.setIIRFilterSize(BME680_FILTER_SIZE_3);
  bme.setGasHeater(320, 150); // 320*C for 150 ms
}

void loop()
{
  float LPG = analogRead(35);
  float NH3 = analogRead(34);
  float NO2 = analogRead(36);
  float CO = analogRead(39);
  float CO2 = sgp.eCO2;
  float VOC = bme.gas_resistance;
  float TVOC = sgp.TVOC;
  float H2 = sgp.rawH2;
  float EtOH = sgp.rawEthanol;
  float altitude = bme.readAltitude(SEALEVELPRESSURE_HPA);

  unsigned long currentMillis = millis();
  if (currentMillis - previousMillis >= interval)
  {
    if (!bme.endReading())
    {
      Serial.println(F("Failed to complete reading :("));
      return;
    }
    Serial.print(F("Reading completed at "));
    Serial.println(millis());
    float completed = millis();

    Serial.print(F("Temperature = "));
    Serial.print(bme.temperature, 1);
    Serial.println(F(" *C"));
    Serial.print(F("Humidity = "));
    Serial.print(bme.humidity, 1);
    Serial.println(F(" %"));

    // Save the last time a new reading was published
    previousMillis = currentMillis;
    //Set values to send
    myData.id = BOARD_ID;
    myData.completed = completed;
    myData.temperature = (bme.temperature);
    myData.humidity = (bme.humidity);
    myData.pressure = (bme.pressure);
    myData.altitude = altitude;
    myData.LPG = LPG;
    myData.CO = CO;
    myData.CO2 = CO2;
    myData.NH3 = NH3;
    myData.NO2 = NO2;
    myData.VOC = VOC;
    myData.TVOC = TVOC;
    myData.H2 = H2;
    myData.EtOH = EtOH;
    myData.readingId = readingId++;

    //Send message via ESP-NOW
    esp_err_t result = esp_now_send(broadcastAddress, (uint8_t *)&myData, sizeof(myData));
    if (result == ESP_OK)
    {
      Serial.println("Sent with success");
    }
    else
    {
      Serial.println("Error sending the data");
    }
  }

  delay(5000);
}

ini:

[env:esp32dev]
platform = espressif32
board = esp32dev
framework = arduino
lib_deps = 
	esp_now
	WiFi
    FS
	ottowinter/ESPAsyncWebServer-esphome@^1.2.7
	https://github.com/arduino-libraries/Arduino_JSON.git
    https://github.com/adafruit/Adafruit_Sensor.git
    https://github.com/adafruit/Adafruit_BME680.git
    https://github.com/adafruit/Adafruit_SGP30.git

Weird, but if the firmware was updated and it’s still showing that, then then the read must be coming from somwhere. Can you narrow it down further by adding Serial.println() statements before and after all your analogRead() calls and some other places in loop? That should tell you at least high-level where the calling code is.

Solved.
This is an ESPNow receiver.
It doesn’t have anything in the analog slots.
The sending unit did have IO2 and IO4 in use.
The error squirted out the ESPNow hole.
Receiver told me about a problem with sender.
Neat.